The Sponsorship deal will last for three years and will start on September 1, on the day of Ukraine vs Kazakhstan match in the 2022 World Cup qualification round.
"VBET is happy for the start of the Ukraine team partnership. We are proud to become a part of this fantastic team and we will do anything for Ukraine fans to be as close to the team as possible.
"And the team managers and players could also feel the support of the 12th player," said Vbet Ukraine chief Georgi Givishvili.
"We welcome VBET to our big football family. I am sure that together we can make the millions favourite game more exciting and interesting for the fans," said Ukraine football association president Andriy Pavelko.